Europium doped zirconia luminescence

Krisjanis Smits , Larisa Grigorjeva a, Donats Millers , Anatolijs Sarakovskis , Agnieszka Opalinska ,
Janusz D. Fidelus , Witold Lojkowski 

The luminescence properties and crystalline structure of ZrO2:Eu nanocrystals doped with different concentrations
of Eu were studied. Luminescence from the Eu2+ state was not observed even if the electrons
and holes were created up to 1019 cm3; thus it was suggested the Eu3+ was not an efficient trap for
electrons possibly due to Eu3+ negative charge relative to the crystalline lattice. The mutual interaction
between Eu3+ ions was not strong up to 5 at.% concentration. The stabilization of ZrO2 tetragonal as well
as cubic structure by Eu3+ is possible.

Optical Materials 32 (2010) 827–831


pdf-iconDownload PDF

The luminescence of ZnO ceramics

L. Grigorjeva , D.Millers , K.Smits , J.Grabis , J.Fidelus , W. qojkowski , T.Chudoba , K.Bienkowski 

The luminescence properties of ZnO ceramics with grains 100-5000 nm sintered by different techniques from nanopowders were studied. The luminescence decay times were compared with that obtained for ZnO singlecrystal. The temperature dependence of non-exponential decay of defect luminescence (2.0-2.6 eV) was measured in wide time, intensity and temperature range.The luminescence decay kinetic at T=20 K shows the decay close to I(t) w t1 dependence. At temperature region 50-250 K the decay kinetics is more complicated since the TSL was observed in this temperature region. It is shown that the luminescence properties of NP and ceramics strongly depend on defect distribution on grains surface
and the volume/surface ratio determine the luminescence decay in ZnO nanostructures and ceramics.

Radiation Measurements


pdf-iconDownload PDF